Journal of Organometallic Chemistry p. 379 - 392 (1987)
Update date:2022-08-05
Topics:
Knoll, Konrad
Huttner, Gottfried
Zsolnai, Laszlo
Orama, Olli
The RP bridged clusters (μ3-RP)Fe3(CO)10 (1) react with diphenylacetylene upon irradiation to yield three different isomers (RP)(PhCCPh)Fe3(CO)9 (2-4) depending on the reaction conditions.X-ray diffraction analysis of the isomers shows that in 2, which appears to be the primary photochemically formed product, the alkyne is inserted between a phosphorous and an iron center of 1.For isomer 3 one of the PFe bonds of the starting cluster 1 is bridged by the alkyne while in 4 the alkyne is inserted into an FeFe edge of 1.These observations suggest that photochemical activation of 1 involves homolytic PFe bond scission with consequent decarbonylation.
Changzhou Sunlight Pharmaceutical Co., Ltd.
Contact:+86-519-83131668;83139028;83138042;83137041
Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Anhui New Star Pharmaceutical Development Co., Ltd
Contact:013956922763
Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)
Contact:+86-571-87046953
Address:No. 37, Qingchun Road
Beijing Mashi Fine Chemical Co.,Ltd.
Contact:+86-10-61271592
Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Guangxi Shanyun Biochemical Science and Technology Co., Ltd
Contact:+86-0772--6828887
Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Doi:10.1016/j.bmc.2009.01.029
(2009)Doi:10.1016/S0040-4020(01)86795-8
(1987)Doi:10.1007/BF00476551
(1987)Doi:10.1016/j.bmcl.2009.02.003
(2009)Doi:10.1021/jm9002582
(2009)Doi:10.1016/j.tet.2009.12.032
(2010)
