REGIO-CONTROLLED FUNCTIONALIZATION OF 2,5-DIMETHYL-2,4-HEXADIENE INTO EPOXY ALCOHOLS BY PHOTOOXYGENATION IN THE PRESENCE OF TITANIUM(IV) OR VANADIUM(V)

DOI: 10.1016/S0040-4039(00)80141-0

Source and publish data:

Tetrahedron Letters p. 531 - 534 (1988)

Update date:2022-08-03

Topics:

Authors:

Adam, Waldemar

Staab, Eugen

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Article abstract of DOI:10.1016/S0040-4039(00)80141-0

Using Ti(OiPr)4 as oxygen transfer catalyst, the diene 1 afforded exclusively the epoxy alcohol 1c, but VO(acac)2 gave exclusively the isomerized epoxy alcohol 2c during its ene reaction with singlet oxygen.

Full text of DOI:10.1016/S0040-4039(00)80141-0

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