STEREOSELECTIVE SYNTHESIS OF C-GLYCOSYL COMPOUNDS via MICHAEL ADDITION OF TRIMETHYLSILYL ENOL ETHERS AND ENAMINES TO HEX-1-ENOPYRAN-3-ULOSES

DOI: 10.1016/S0008-6215(00)90876-0

Source and publish data:

Carbohydrate Research p. 25 - 34 (1987)

Update date:2022-07-29

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Authors:

Kunz, Horst

Mueller, Bernd

Weissmueller, Joachim

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Article abstract of DOI:10.1016/S0008-6215(00)90876-0

The titanium(IV)-catalyzed addition of trimethylsilyl enol ethers to 2,4,6-tri-O-acylhex-1-enopyran-3-uloses (3 and 4) gave stereoselectively 3,6-di-O-acyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose derivatives.The formation of the C-glycosyl bond was

Full text of DOI:10.1016/S0008-6215(00)90876-0

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