A convenient synthesis of ethyl 3,3,3,-trifluoropropanoate and its 2-bromo derivative

DOI: 10.1016/S0022-1139(00)82015-1

Source and publish data:

Journal of Fluorine Chemistry p. 183 - 189 (1987)

Update date:2022-07-29

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Authors:

Molines Molines

Wakselman

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Article abstract of DOI:10.1016/S0022-1139(00)82015-1

Ethyl 3,3,3-trifluoropropanoate and ethyl 2-bromo-3,3,3-trifluoropropanoate have been synthesized. A common intermediate ethyl 3-chloro (or 3-bromo)-3,3-difluoropropanoate is involved in the two syntheses. These esters are obtained by oxidation of the corresponding acetals resulting from the radical addition of CF₂BrCl or CF₂Br₂ to ethyl vinyl ether.

Full text of DOI:10.1016/S0022-1139(00)82015-1

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