Journal of Fluorine Chemistry p. 183 - 189 (1987)
Update date:2022-07-29
Topics:
Molines
Wakselman
Ethyl 3,3,3-trifluoropropanoate and ethyl 2-bromo-3,3,3-trifluoropropanoate have been synthesized. A common intermediate ethyl 3-chloro (or 3-bromo)-3,3-difluoropropanoate is involved in the two syntheses. These esters are obtained by oxidation of the corresponding acetals resulting from the radical addition of CF2BrCl or CF2Br2 to ethyl vinyl ether.
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Doi:10.1016/S0040-4039(00)96330-5
(1987)Doi:10.1016/S0040-4039(00)96769-8
(1987)Doi:10.1016/S0040-4039(00)74069-X
(1993)Doi:10.1134/S1070428008090212
(2008)Doi:10.1039/b822734a
(2009)Doi:10.1016/S1387-7003(03)00053-4
(2003)
