Organic Letters p. 2377 - 2379 (2009)
Update date:2022-07-30
Topics:
Nishikata, Takashi
Lipshutz, Bruce H.
The "trick" to carrying out regiocontrolled aminations of allylic alcohols in water as the only medium is use of a nanomicelle's interior as the organic reaction solvent. When HCO2Me is present, along with the proper base and source of catalytic Pd, allylic amines are cleanly formed at room temperature.
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