Substituted ketene elimination from acid chlorides induced by ruthenium(0) compounds

DOI: 10.1016/0022-328X(88)80510-2

Source and publish data:

Journal of Organometallic Chemistry p. 255 - 260 (1988)

Update date:2022-07-29

Topics:

Authors:

Singh, Shanti

Baird, Michael C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(88)80510-2

The compound Ru(CO)2(triphos) (triphos=MeC(CH2PPh2)3) reacts with a number of acid chlorides RR'CHCOCl to form Cl and the corresponding substituted ketenes RR'CCO.A quantitative study of the reaction of Ph2CHCOCl shows that Ph2CCO is formed in a 1:1 stoichiometry.The compound Ru(CO)3(PPh3)2 also reacts with Ph2CHCOCl forming Ph2CCO and the unstable hydride Cl, the chemistry of which is also reported.

Full text of DOI:10.1016/0022-328X(88)80510-2

Products guided by the article

Product name:RuH(CO)3(P(C₆H₅)3)2⁽¹⁺⁾*CF₃COO^(1-)={RuH(CO)3(P(C₆H₅)3)2}(CF₃COO)

Cas No:115979-98-1

R&D Labs maybe for 115979-98-1

Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA
Hebei Lead Bio-Chemicals Co., Ltd.

website:http://www.ldbiochem.com

Contact:+86-311-87826503

Address:481, Heping West Road, Shijiazhuang,China
Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang

Relevant to this article

Hybrid calix[4]arenes via ionic hydrogenation and transition-metal-mediated processes

Doi:10.1021/ol900714n
(2009)
STEREOCHEMICAL ASPECTS OF ASYMMETRIC DIELS-ALDER REACTION CATALYZED BY CHIRAL ALKOXYALUMINUM DICHLORIDES

Doi:10.1016/S0040-4039(00)96814-X
(1987)
Reactive alkyne complexes of tantalum and their metallacyclization chemistry: Models for alkyne cyclotrimerization by the early transition metals

Doi:10.1021/om00099a031
(1988)
Forging C?S(Se) Bonds by Nickel-catalyzed Decarbonylation of Carboxylic Acid and Cleavage of Aryl Dichalcogenides

Doi:10.1002/ejoc.202100115
(2021)
From one to three: A serine derivate manipulated homochiral metal-organic framework

Doi:10.1039/b823323c
(2009)
Efficient syntheses of crispine A and harmicine by Rh-catalyzed cyclohydrocarbonylation

Doi:10.1021/ol900702t
(2009)

Article Doi