CONSTRUCTION OF CHIRAL QUARTERNARY CARBON CENTERS USING 3-SUBSTITUTED 5-TRIMETHYLSILYL-2-CYCLOHEXENONES: SYNTHESIS OF (+)-α-CUPARENONE

DOI: 10.1016/S0040-4039(00)80086-6

Source and publish data:

Tetrahedron Letters p. 325 - 328 (1988)

Update date:2022-09-26

Topics:

Authors:

Asaoka, Morio

Takenouchi, Kazuya

Takei, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)80086-6

1,4-Addition of Grignard reagents to 3-substituted 5-trimethylsilyl-2-cyclohexenones proceeded in a highly diastereoselective manner.By utilizing the reaction, (+)-α-cuparenone was synthesized starting from enantiomerically pure 3-p-tolylthio-5-(trimethyl

Full text of DOI:10.1016/S0040-4039(00)80086-6

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Product name:(+/-)-3-p-tolylthio-5-(trimethylsilyl)cyclohexanone

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