Tetrahedron Letters p. 325 - 328 (1988)
Update date:2022-09-26
Topics:
Asaoka, Morio
Takenouchi, Kazuya
Takei, Hisashi
1,4-Addition of Grignard reagents to 3-substituted 5-trimethylsilyl-2-cyclohexenones proceeded in a highly diastereoselective manner.By utilizing the reaction, (+)-α-cuparenone was synthesized starting from enantiomerically pure 3-p-tolylthio-5-(trimethyl
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