Copper(I) Iodide-Assisted Halogen Exchange at Vinylic Positions. Conversion of Vinyl Vinylene, and Vinylidene Bromides to the Corresponding Iodo Analogs

DOI: 10.1055/s-1988-27527

Source and publish data:

Synthesis p. 236 - 238 (1988)

Update date:2022-08-04

Topics: Vinyl Copper(I) Iodide Bromides Vinylidene Halogen Exchange Vinylene

Authors:

Suzuki, Hitomi

Aihara, Mie

Yamamoto, Hidetoshi

Takamato, Yuuko

Ogawa, Takuji

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Article abstract of DOI:10.1055/s-1988-27527

The title bromo olefins undergo the copper(I) iodide-mediated exchange with iodide ion in hot hexamethylenephosphoric triamide to give the corresponding iodo analogs in moderate to good yield.

Full text of DOI:10.1055/s-1988-27527

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Product name:1-Hexene, 2-iodo-5-methyl-

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