Copper(I) Iodide-Assisted Halogen Exchange at Vinylic Positions. Conversion of Vinyl Vinylene, and Vinylidene Bromides to the Corresponding Iodo Analogs

DOI: 10.1055/s-1988-27527

Source and publish data:

Synthesis p. 236 - 238 (1988)

Update date:2022-08-04

Topics: Vinyl Copper(I) Iodide Bromides Vinylidene Halogen Exchange Vinylene

Authors:

Suzuki, Hitomi

Aihara, Mie

Yamamoto, Hidetoshi

Takamato, Yuuko

Ogawa, Takuji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1988-27527

The title bromo olefins undergo the copper(I) iodide-mediated exchange with iodide ion in hot hexamethylenephosphoric triamide to give the corresponding iodo analogs in moderate to good yield.

Full text of DOI:10.1055/s-1988-27527

Products guided by the article

Product name:1-Hexene, 2-iodo-5-methyl-

Cas No:116544-99-1

R&D Labs maybe for 116544-99-1

Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA

Relevant to this article

Studies toward the duocarmycin prodrugs for the antibody prodrug therapy approach

Doi:10.1016/j.tetlet.2009.03.205
(2009)
CuBr-mediated oxyalkylation of vinylarenes under aerobic conditions via cleavage of sp³ C-H bonds α to oxygen

Doi:10.1021/ol900947d
(2009)
Zn(OAc)₂-catalyzing ring-opening polymerization of N-carboxyanhydrides for the synthesis of well-defined polypeptides

Doi:10.3390/molecules23040760
(2018)
Multi-catalysis cascade reactions based on the methoxycarbonylketene platform: Diversity-oriented synthesis of functionalized non-symmetrical malonates for agrochemicals and pharmaceuticals

Doi:10.1039/b901652j
(2009)
Cationic η³-allyl sulfide complexes of nickel(II) for the polymerization of butadiene in aqueous emulsion

Doi:10.1016/j.jorganchem.2009.11.041
(2010)
Interpenetrating digold(I) diacetylide macrocycles

Doi:10.1039/b201832b
(2002)

Article Doi