Synthesis of μ-Carbene and μ-Carbyne Complexes of Rhodium and Cobalt from Substituted Diazirines. Crystal Structures of 5-C5Me5)2(CO)2> and 5-C5Me5)2(μ-CO)(μ-C6H4Me-4)>

DOI: 10.1039/DT9910001417

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1417 - 1425 (1991)

Update date:2022-09-26

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Authors:

Avent, Anthony G.

Benyunes, Stephen A.

Chaloner, Penny A.

Gotts, Nigel G.

Hitchcock, Peter B.

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Article abstract of DOI:10.1039/DT9910001417

The reaction of aryl(methoxy)diazirines with 5-C5Me5)2(μ-CO)2> (M = Rh or Co) affords the μ-carbene complexes 5-C5Me5)(CO)2<μ-CR(OMe)>> (R = aryl) in excellent yield.The carbonyl groups are terminal in the rhodium complexes

Full text of DOI:10.1039/DT9910001417

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