A versatile process for the syntheses of very long chain alkanes, functionalised derivatives and some branched chain hydrocarbons

DOI: 10.1039/p19960001635

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1635 - 1645 (1996)

Update date:2022-08-03

Topics: Syntheses Alkane Functionalized Experimental terms

Authors:

Brooke, Gerald M.

Burnett, Simon

Mohammed, Shahid

Proctor, David

Whiting, Mark C.

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Article abstract of DOI:10.1039/p19960001635

An earlier method for synthesising very long straight-chain alkanes of very specific lengths has been improved to give, in some cases, gram amounts of materials. Eleven compounds have been made: C₉₈H₁₉₈, C₁₂₂H₂₄₆, C₁₆₂H₃₂₆, C₁₉₄H₃₉₀, C₁₉₈H₃₉₈, C₂₁₀H₄₂₂, C₂₄₂H₄₈₆, C₂₄₆H₄₉₄, C₂₅₈H₅₁₈, C₂₉₄H₅₉₀ and C₃₉₀H₇₈₂. The self-condensation reaction of one of the intermediate aldehydes enabled two chain-branched hydrocarbons to be obtained: C₉₆H₁₉₃CHRC₉₄H₁₈₉ where R = CH₃ and CH₃(CH₂)₃. Three long-chain compounds containing carboxylic acid groups have been prepared: CH₃(CH₂)₁₉₀CO₂H, HO₂C(CH₂)₄₈CO₂H and HO₂C(CH₂)₁₉₂CO₂H. Copyright 1996 by the Royal Society of Chemistry.

Full text of DOI:10.1039/p19960001635

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