Tetrahedron Letters p. 637 - 640 (1987)
Update date:2022-08-03
Topics:
Hashimoto, Shun-ichi
Shinoda, Tomohiro
Shimada, Yasunaga
Honda, Takeshi
Ikegami, Shiro
A key intermediate for the synthesis of isocarbacyclin, a promising therapeutic agent for cardiovascular and circulatory disorders, has been synthesized from (R)-(+)-methyl 2-oxo-1-cyclopentaneacetate by employing rhodium(II)-catalyzed intramolecular C-H insertion reaction of α-diazo β-keto ester as a key step.
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