Intermediates in the Epoxidation of Alkenes by Cytochrome P-450 Models. 2. Use of the trans-2,trans-3-Diphenylcyclopropyl Substituent in a Search for Radical Intermediates

DOI: 10.1021/ja00230a039

Source and publish data:

Journal of the American Chemical Society p. 7512 - 7519 (1988)

Update date:2022-08-03

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Authors:

Castellino, Angelo J.

Bruice, Thomas C.

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Article abstract of DOI:10.1021/ja00230a039

(Z)-1,2-Bis(trans-2,trans-3-diphenylcyclopropyl)ethene (1-Z) has been used to search for radical intermediates in the epoxidation reactions of cytochrome P-450 model systems.The studied systems used the following as catalysts: (meso-tetrakis(pentafluoroph

Full text of DOI:10.1021/ja00230a039

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