The coordination chemistry of iminooxosulphuranes. The osmium and iridium series (ML = OsNO,IrCO;A = O, CH2, S, NR; R = o-tolyl, p-tolyl and p-tosyl)

Article abstract of DOI:10.1016/0022-328X(90)87181-C

The preparation and characterisation of the two analogous series of compounds (A = O, CH2, S, NR; R = C6H4Me-4, C6H4Me-2, SO2C6H4Me-4) and (A = O, S, NSO2C6H4Me-4) are described.A comparison of spectroscopic data for the complex supports the isolobal relationship between the molecules OSA.