Tetrahedron p. 573 - 582 (1986)
Update date:2022-07-31
Topics:
Valverde, Serafin
Lopez, Jose Cristobal
Rabanal, Rosa M.
Escudero, Javier
Abietic acid methyl ester reacts regioselectively with m-chloroperbenzoic acid, in the presence of water to yield a mixture of the two epimeric 13,14-monoepoxides.These epoxides further react affording a mixture of 1,2- and 1,4-unsaturated diols.The overall yield of the reaction is acceptably good (70-80percent).The formation of these and other products are discussed.
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