Le O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie (C2H5O)2P(O)C(Cl)Si(CH3)3Li

DOI: 10.1016/0022-328X(88)80003-2

Source and publish data:

Journal of Organometallic Chemistry p. 295 - 304 (1988)

Update date:2022-08-03

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Authors:

Teulade, Marie-Paule

Savignac, Philippe

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Article abstract of DOI:10.1016/0022-328X(88)80003-2

Silylation of either chloromethyl- or trichloromethyl-phosphonate in the presence of excess n-BuLi leads to the quantitative generation of lithiated trimethylsilylchloromethylphosphonates.This stable type of anion can be protonated, deuterated or alkylate

Full text of DOI:10.1016/0022-328X(88)80003-2

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