STEREOSELECTIVE CYANOHYDRIN-FORMING REACTIONS OF CHIRAL α-AMINO ALDEHYDES

DOI: 10.1016/0040-4039(88)85144-X

Source and publish data:

Tetrahedron Letters p. 3295 - 3298 (1988)

Update date:2022-07-30

Topics:

Authors:

Reetz, M. T.

Drewes, M. W.

Harms, K.

Reif, W.

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Article abstract of DOI:10.1016/0040-4039(88)85144-X

The Lewis acid mediated cyanohydrin-forming addition of Me3SiCN to optically active α-dibenzylamino aldehydes 2 occurs stereoselectively.Chelation controlled adducts 3 result if MgBr2 or TiCl4 is used, whereas the diastereomers 4 are obtained upon employi

Full text of DOI:10.1016/0040-4039(88)85144-X

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