CATIONIC COMPLEXES OF RHODIUM(I) CATALYSTS IN THE HOMOGENEOUS O2-OXIDATION OF TERMINAL ALKENES TO METHYL KETONES

DOI: 10.1016/0022-328X(85)87071-6

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 146 (1985)

Update date:2022-08-02

Topics:

Authors:

Bressan, Mario

Morandini, Franco

Morvillo, Antonio

Rigo, Pierluigi

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Article abstract of DOI:10.1016/0022-328X(85)87071-6

⁺, ⁺ and ⁺ complexes are effective as catalysts for the oxidation by dioxygen of terminal olefins to methyl ketones.The complexes act as monooxygenases, the second oxygen atom being transferred to the alcohol solvent

Full text of DOI:10.1016/0022-328X(85)87071-6

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Product name:Rh((C₆H₅)2P(CH₂)SC₆H₅)2⁽¹⁺⁾*BF₄^(1-) = Rh((C₆H₅)2P(CH₂)SC₆H₅)2BF₄

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