AN OBSERVATION OF DIASTEREOFACE SELECTIVITY IN THERMAL REACTIONS BETWEEN δ-ALKOXYALLYLSTANNANES AND ALDEHYDES

DOI: 10.1016/S0040-4039(00)87912-5

Source and publish data:

Tetrahedron Letters p. 2479 - 2482 (1988)

Update date:2022-08-04

Topics:

Authors:

Mortlock, Simon V.

Thomas, Eric J.

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Article abstract of DOI:10.1016/S0040-4039(00)87912-5

The δ-alkoxyallylstannanes (4) and (5) react stereoselectively on heating with p-nitrobenzaldehyde to provide the homoallylic alcohols (14) - (17), with (14) : (15) = 82 : 18; (16) : (17) = 73 : 27

Full text of DOI:10.1016/S0040-4039(00)87912-5

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