ALDOL-TYPE REACTIONS BETWEEN TRIMETHYLSILYL ENOL ETHERS AND ACETALS WITH THE AID OF RHODIUM COMPLEX

DOI: 10.1016/S0040-4039(00)96938-7

Source and publish data:

Tetrahedron Letters p. 6657 - 6660 (1987)

Update date:2022-08-04

Topics:

Authors:

Sato, Susumu

Matsuda, Isamu

Izum, Yusuke

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Article abstract of DOI:10.1016/S0040-4039(00)96938-7

Aldol type reactions of trimethylsilyl enol ethers with acetals, ketals and orthoesters are successfully performed with the aid of a catalytic amount of rhodium complex Rh4(CO)12 or (Rh(COD)(DPPB))(1+)*ClO4(1-), under neutral conditions.

Full text of DOI:10.1016/S0040-4039(00)96938-7

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