ALDOL-TYPE REACTIONS BETWEEN TRIMETHYLSILYL ENOL ETHERS AND ACETALS WITH THE AID OF RHODIUM COMPLEX

DOI: 10.1016/S0040-4039(00)96938-7

Source and publish data:

Tetrahedron Letters p. 6657 - 6660 (1987)

Update date:2022-08-04

Topics:

Authors:

Sato, Susumu

Matsuda, Isamu

Izum, Yusuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96938-7

Aldol type reactions of trimethylsilyl enol ethers with acetals, ketals and orthoesters are successfully performed with the aid of a catalytic amount of rhodium complex Rh4(CO)12 or (Rh(COD)(DPPB))(1+)*ClO4(1-), under neutral conditions.

Full text of DOI:10.1016/S0040-4039(00)96938-7

Products guided by the article

Product name:3-methoxy-1-phenyl-4-trimethylsiloxy-1-pentanone

Cas No:119582-54-6

R&D Labs maybe for 119582-54-6

Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
Ningbo J&S Botanics Inc.

Contact:86-574-26865651

Address:529 YuanBaoShan Road, Beilun District
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Heliosense Biotechnologies, Inc.

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506

Relevant to this article

Fluorinated Aromatic Monomers as Building Blocks to Control α-Peptoid Conformation and Structure

Doi:10.1021/jacs.8b13498
(2019)
Discovery of First-In-Class Potent and Selective Tropomyosin Receptor Kinase Degraders

Doi:10.1021/acs.jmedchem.0c01342
(2020)
Synthesis and cytotoxic evaluation of 6-(3-pyrazolylpropyl) derivatives of 1,4-naphthohydroquinone-1,4-diacetate

Doi:10.1002/ardp.200900041
(2009)
Proline-catalyzed synthesis of 5-aryl-2-oxazolidinones from carbon dioxide and aziridines under solvent-free conditions

Doi:10.1080/00397911.2010.521903
(2012)
Chemical conversion of corticosteroids to 3α,5α-tetrahydro derivatives. Synthesis of allotetrahydro-11-deoxycortisol glucuronides

Doi:10.1248/cpb.33.4281
(1985)
First example of s-BuLi/(-)-sparteine-mediated chiral deprotonation of a piperazine and proof of the sense of induction

Doi:10.1055/s-2008-1042905
(2008)

Article Doi