The Preparation of Optically Active Δ2-Isoxazolines. A Model for Asymmetric Induction in the Non Lewis Acid Catalyzed Reactions of Oppolzer's Chiral Sultam

DOI: 10.1016/0040-4039(88)85291-2

Source and publish data:

Tetrahedron Letters p. 3555 - 3558 (1988)

Update date:2022-09-26

Topics:

Authors:

Curran, Dennis P.

Kim, Byeang Hyean

Daugherty, James

Heffner, Timothy, A.

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Article abstract of DOI:10.1016/0040-4039(88)85291-2

Good diastereoselectivity (ca. 90/10) is reported in the cycloaddition reactions of Oppolzer's chiral sultam with nitrile oxides.A model is proposed which may apply to other non Lewis acid promoted reactions of this sultam.

Full text of DOI:10.1016/0040-4039(88)85291-2

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