STEREOCONTROLLED SYNTHESIS OF A C14-C20 BUILDING BLOCK FOR AMPHOTERICIN B USING A NOVEL WITTIG REARRANGEMENT

DOI: 10.1016/S0040-4039(00)82180-2

Source and publish data:

Tetrahedron Letters p. 5747 - 5750 (1988)

Update date:2022-08-05

Topics:: Authors:

Bruecker, Reinhard

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Article abstract of DOI:10.1016/S0040-4039(00)82180-2

The C14-C20 unit 11 of the polyene macrolide antibiotic amphotericin B (1) was synthesized from L-arabinose in 13 steps.The key step 7 -> 10 features diastereocontrol through asymmetric induction in a novel <2,3> Wittig rearrangement.

Full text of DOI:10.1016/S0040-4039(00)82180-2

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Article Doi

STEREOCONTROLLED SYNTHESIS OF A C14-C20 BUILDING BLOCK FOR AMPHOTERICIN B USING A NOVEL WITTIG REARRANGEMENT

DOI: 10.1016/S0040-4039(00)82180-2

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0040-4039(00)82180-2

Full text of DOI:10.1016/S0040-4039(00)82180-2

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