Tetrahedron Letters p. 5747 - 5750 (1988)
Update date:2022-08-05
Topics:
Bruecker, Reinhard
The C14-C20 unit 11 of the polyene macrolide antibiotic amphotericin B (1) was synthesized from L-arabinose in 13 steps.The key step 7 -> 10 features diastereocontrol through asymmetric induction in a novel <2,3> Wittig rearrangement.
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Doi:10.1055/s-0029-1216900
(2009)Doi:10.1021/ja905990u
(2009)Doi:10.1021/jo062151b
(2007)Doi:10.1021/jm970200u
(1997)Doi:10.1016/0040-4039(88)85102-5
(1988)Doi:10.1007/BF00755687
(1988)
