New synthetic procedures to Catena-phosphorus cations: Preparation and dissociation of the first cyclo-phosphino-halophosphonium salts

DOI: 10.1021/ja907693f

Source and publish data:

Journal of the American Chemical Society p. 17943 - 17953 (2009)

Update date:2022-07-29

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Authors:

Weigand, Jan J.

Burford, Neil

Davidson, Reagan J.

Cameron, T. Stanley

Seelheim, Patrick

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Article abstract of DOI:10.1021/ja907693f

Chlorination of 1,2,3,4-tetracyclohexyl-cyclo-tetraphosphine (2) by PhICl₂ or PCl₅ in the presence of Me₃SiOTf or GaCl₃ provides a stepwise approach to salts of the first cyclo-phosphino-chlorophosphonium cation

Full text of DOI:10.1021/ja907693f

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