Tetrahedron Letters p. 5467 - 5470 (1986)
Update date:2022-08-05
Topics:
Oppolzer, Wolfgang
Cunningham, Allan F.
The sesquiterpene (+/-)chokol-A (1) was synthesized in a diastereoselective manner starting from 1-hexen-5-one-trisylhydrazone (5).The key step 7 -> 8 involves the regio- and stereo-selective magnesium-ene reaction 4 -> 3.
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