Journal of the American Chemical Society p. 17748 - 17749 (2009)
Update date:2022-09-26
Topics: Suzuki-Miyaura coupling Palladium catalyst Organic halide Sulfamates Carbonates Pseudohalide
Quasdorf, Kyle W.
Riener, Michelle
Petrova, Krastina V.
Garg, Neil K.
(Chemical Equation Presented) The first Suzuki-Miyaura cross-couplings of carbamates, carbonates, and sulfamates is described. The method provides a powerful means of using simple derivatives of phenol as precursors to polysubstituted aromatic compounds, as exemplified by a concise synthesis of the anti-inflammatory drug flurbiprofen.
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