OXIDATION OF ENAMINES TO α-HYDROXY KETONES AND α-AMINO KETONES USING N-SULFONYLOXAZIRIDINES

DOI: 10.1016/S0040-4039(00)80496-7

Source and publish data:

Tetrahedron Letters p. 4365 - 4368 (1988)

Update date:2022-09-26

Topics:

Authors:

Davis, Franklin A.

Sheppard, Aurelia C.

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Article abstract of DOI:10.1016/S0040-4039(00)80496-7

Tri-substituted enamines are oxidized to α-hydroxy ketones by N-sulfonyloxaziridines while di-substituted enamines are oxidized to α-amino ketones.A unified mechanism for the formation of both α-hydroxy ketones and α-amino ketones is proposed.

Full text of DOI:10.1016/S0040-4039(00)80496-7

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