Oxygenated Allylic Silanes: Useful Homoenolate Equivalents for the Stereoselective C-Glycosidation of Pyranoside Derivatives

DOI: 10.1021/jo00270a005

Source and publish data:

Journal of Organic Chemistry p. 2034 - 2038 (1989)

Update date:2022-09-26

Topics:

Authors:

Panek, James S.

Sparks, Michelle A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00270a005

Acylated C1-oxygenated allylic silanes, <1-(acetyloxy)-2-propenyl>trimethylsilane (1a), <1-(acetyloxy)-2-methyl-2-propenyl>trimethylsilane (1b), and ethyl 2-propenyltrimethylsilane-1-carbonate (1c), function as homoenolate equivalents in BF3*OEt2-catalyze

Full text of DOI:10.1021/jo00270a005

Products guided by the article

Product name:Acetic acid (E)-2-methyl-3-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-propenyl ester

Cas No:120520-64-1

R&D Labs maybe for 120520-64-1

Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Chengdu Green Young Biopharmaceutical INC

Contact:+86-28-85337952

Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000

Relevant to this article

Biomimetic synthesis of natural and "unnatural" lignans by oxidative coupling of caffeic esters

Doi:10.1002/ejoc.200900804
(2009)
Total synthesis of a library of designed hybrids of the microtubule-stabilising anticancer agents taxol, discodermolide and dictyostatin

Doi:10.1039/b921237j
(2010)
A convenient new synthesis of quaternary ammonium glucuronides of drug molecules

Doi:10.1016/j.tet.2009.10.113
(2010)
Synthesis of nalidixic acid based hydrazones as novel pesticides

Doi:10.1021/jf904144e
(2010)
A new, flexible N,N,N-Tripodal facially capping ligand system: Synthesis and structural characterization of β-Triketimines and their M(CO) ₃ complexes (M = Cr, Mo, W)

Doi:10.1002/ejic.200801022
(2009)
Synthesis and optical characterization of novel azacrown ethers containing an acridinone or an N-methylacridinone unit as potential fluorescent chemosensors

Doi:10.1016/j.tet.2009.10.076
(2010)

Article Doi