Oxygenated Allylic Silanes: Useful Homoenolate Equivalents for the Stereoselective C-Glycosidation of Pyranoside Derivatives

DOI: 10.1021/jo00270a005

Source and publish data:

Journal of Organic Chemistry p. 2034 - 2038 (1989)

Update date:2022-09-26

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Authors:

Panek, James S.

Sparks, Michelle A.

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Article abstract of DOI:10.1021/jo00270a005

Acylated C1-oxygenated allylic silanes, <1-(acetyloxy)-2-propenyl>trimethylsilane (1a), <1-(acetyloxy)-2-methyl-2-propenyl>trimethylsilane (1b), and ethyl 2-propenyltrimethylsilane-1-carbonate (1c), function as homoenolate equivalents in BF3*OEt2-catalyze

Full text of DOI:10.1021/jo00270a005

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