Tetrahedron Letters p. 5209 - 5212 (1988)
Update date:2022-07-30
Topics:
Merritt, John E.
Sasson, Marvin
Kates, Steven A.
Snider, Barry B.
Oxidative free radical cyclizations of β-ketoesters 1,5,11, and 14 with Mn(OAc)3*2H2O and Cu(OAc)2*H2O proceed in moderate yield to give seven- and eight-membered rings.The regiochemistry of the cyclization and oxidative termination are described.
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Doi:10.1016/S0040-4039(00)82291-1
(1988)Doi:10.1055/s-0031-1289652
(2012)Doi:10.1080/10426500802591630
(2009)Doi:10.1021/acs.orglett.5b01590
(2015)Doi:10.1016/j.tet.2009.11.018
(2010)Doi:10.1021/ol403075u
(2014)