FORMATION OF SEVEN- AND EIGHT-MEMBERED RINGS BY MANGANESE(III)-BASED OXIDATIVE FREE RADICAL CYCLIZATION.

DOI: 10.1016/S0040-4039(00)80718-2

Source and publish data:

Tetrahedron Letters p. 5209 - 5212 (1988)

Update date:2022-07-30

Topics:

Authors:

Merritt, John E.

Sasson, Marvin

Kates, Steven A.

Snider, Barry B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80718-2

Oxidative free radical cyclizations of β-ketoesters 1,5,11, and 14 with Mn(OAc)3*2H2O and Cu(OAc)2*H2O proceed in moderate yield to give seven- and eight-membered rings.The regiochemistry of the cyclization and oxidative termination are described.

Full text of DOI:10.1016/S0040-4039(00)80718-2

Products guided by the article

Product name:Cyclohexanecarboxylic acid, 1-chloro-2-methylene-6-oxo-, ethyl ester

Cas No:120985-29-7

R&D Labs maybe for 120985-29-7

Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Chongqing maohuan Chemicals Co., Ltd

website:http://www.bschem.com

Contact:+86 13996103726

Address:Chongqing Nan'an District Tu Town
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.

Relevant to this article

THE STEREOSELECTIVITY OF RING-OPENING OF 3-SUBSTITUTED CYCLOPROPENES AND INTERMOLECULAR TRAPPING OF DERIVED VINYLCARBENES

Doi:10.1016/S0040-4039(00)82291-1
(1988)
First synthesis of benzopyridoiodolium salts and twofold Buchwald-Hartwig amination for the total synthesis of quindoline

Doi:10.1055/s-0031-1289652
(2012)
Synthesis and in vitro anti-hiv activity of some New Schiff base ligands derived from 5-Amino-4-phenyl-4H-1,2,4-triazole-3-thiol and their metal complexes

Doi:10.1080/10426500802591630
(2009)
Facile Synthesis of Carbazoles via a Tandem Iodocyclization with 1,2-Alkyl Migration and Aromatization

Doi:10.1021/acs.orglett.5b01590
(2015)
Chiral zinc(II) and copper(II)-catalyzed asymmetric ring-opening reactions of meso-epoxides with aniline and indole derivatives

Doi:10.1016/j.tet.2009.11.018
(2010)
Catalytic enantioselective mannich-type reaction via a chiral silver enolate

Doi:10.1021/ol403075u
(2014)

Article Doi