FORMATION OF SEVEN- AND EIGHT-MEMBERED RINGS BY MANGANESE(III)-BASED OXIDATIVE FREE RADICAL CYCLIZATION.

DOI: 10.1016/S0040-4039(00)80718-2

Source and publish data:

Tetrahedron Letters p. 5209 - 5212 (1988)

Update date:2022-07-30

Topics:

Authors:

Merritt, John E.

Sasson, Marvin

Kates, Steven A.

Snider, Barry B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80718-2

Oxidative free radical cyclizations of β-ketoesters 1,5,11, and 14 with Mn(OAc)3*2H2O and Cu(OAc)2*H2O proceed in moderate yield to give seven- and eight-membered rings.The regiochemistry of the cyclization and oxidative termination are described.

Full text of DOI:10.1016/S0040-4039(00)80718-2

Products guided by the article

Product name:Cyclohexanecarboxylic acid, 1-chloro-2-methylene-6-oxo-, ethyl ester

Cas No:120985-29-7

R&D Labs maybe for 120985-29-7

Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Changsha Yihai Chemical Technology Co.,ltd

website:http://www.cs-yihai.com/

Contact:0731- 85620465

Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China

Relevant to this article

THE STEREOSELECTIVITY OF RING-OPENING OF 3-SUBSTITUTED CYCLOPROPENES AND INTERMOLECULAR TRAPPING OF DERIVED VINYLCARBENES

Doi:10.1016/S0040-4039(00)82291-1
(1988)
First synthesis of benzopyridoiodolium salts and twofold Buchwald-Hartwig amination for the total synthesis of quindoline

Doi:10.1055/s-0031-1289652
(2012)
Synthesis and in vitro anti-hiv activity of some New Schiff base ligands derived from 5-Amino-4-phenyl-4H-1,2,4-triazole-3-thiol and their metal complexes

Doi:10.1080/10426500802591630
(2009)
Facile Synthesis of Carbazoles via a Tandem Iodocyclization with 1,2-Alkyl Migration and Aromatization

Doi:10.1021/acs.orglett.5b01590
(2015)
Chiral zinc(II) and copper(II)-catalyzed asymmetric ring-opening reactions of meso-epoxides with aniline and indole derivatives

Doi:10.1016/j.tet.2009.11.018
(2010)
Catalytic enantioselective mannich-type reaction via a chiral silver enolate

Doi:10.1021/ol403075u
(2014)

Article Doi