FORMATION OF SEVEN- AND EIGHT-MEMBERED RINGS BY MANGANESE(III)-BASED OXIDATIVE FREE RADICAL CYCLIZATION.

DOI: 10.1016/S0040-4039(00)80718-2

Source and publish data:

Tetrahedron Letters p. 5209 - 5212 (1988)

Update date:2022-07-30

Topics:

Authors:

Merritt, John E.

Sasson, Marvin

Kates, Steven A.

Snider, Barry B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80718-2

Oxidative free radical cyclizations of β-ketoesters 1,5,11, and 14 with Mn(OAc)3*2H2O and Cu(OAc)2*H2O proceed in moderate yield to give seven- and eight-membered rings.The regiochemistry of the cyclization and oxidative termination are described.

Full text of DOI:10.1016/S0040-4039(00)80718-2

Products guided by the article

Product name:Cyclohexanecarboxylic acid, 1-chloro-2-methylene-6-oxo-, ethyl ester

Cas No:120985-29-7

R&D Labs maybe for 120985-29-7

SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Hubei Vanz Pharm Co.,Ltd

website:http://www.vanzpharm.com/en/index.html

Contact:86-27-84492310

Address:FANHU INDUSTRY PARK

Relevant to this article

THE STEREOSELECTIVITY OF RING-OPENING OF 3-SUBSTITUTED CYCLOPROPENES AND INTERMOLECULAR TRAPPING OF DERIVED VINYLCARBENES

Doi:10.1016/S0040-4039(00)82291-1
(1988)
First synthesis of benzopyridoiodolium salts and twofold Buchwald-Hartwig amination for the total synthesis of quindoline

Doi:10.1055/s-0031-1289652
(2012)
Synthesis and in vitro anti-hiv activity of some New Schiff base ligands derived from 5-Amino-4-phenyl-4H-1,2,4-triazole-3-thiol and their metal complexes

Doi:10.1080/10426500802591630
(2009)
Facile Synthesis of Carbazoles via a Tandem Iodocyclization with 1,2-Alkyl Migration and Aromatization

Doi:10.1021/acs.orglett.5b01590
(2015)
Chiral zinc(II) and copper(II)-catalyzed asymmetric ring-opening reactions of meso-epoxides with aniline and indole derivatives

Doi:10.1016/j.tet.2009.11.018
(2010)
Catalytic enantioselective mannich-type reaction via a chiral silver enolate

Doi:10.1021/ol403075u
(2014)

Article Doi