FORMATION OF SEVEN- AND EIGHT-MEMBERED RINGS BY MANGANESE(III)-BASED OXIDATIVE FREE RADICAL CYCLIZATION.

DOI: 10.1016/S0040-4039(00)80718-2

Source and publish data:

Tetrahedron Letters p. 5209 - 5212 (1988)

Update date:2022-07-30

Topics:

Authors:

Merritt, John E.

Sasson, Marvin

Kates, Steven A.

Snider, Barry B.

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Article abstract of DOI:10.1016/S0040-4039(00)80718-2

Oxidative free radical cyclizations of β-ketoesters 1,5,11, and 14 with Mn(OAc)3*2H2O and Cu(OAc)2*H2O proceed in moderate yield to give seven- and eight-membered rings.The regiochemistry of the cyclization and oxidative termination are described.

Full text of DOI:10.1016/S0040-4039(00)80718-2

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