Journal of Organic Chemistry p. 5349 - 5353 (1991)
Update date:2022-08-05
Topics:
Andersson, Pher G.
Baeckvall, Jan-E.
The total syntheses of marmelo oxides A and B and a terpene alcohol found in peppermint oil are described.The key steps in these syntheses are the regioselective palladium-catalyzed allylic substitution of 4 and 11 to 6a and 12, respectively, and the regioselective palladium-catalyzed cyclization of 8 and 14 to 9a, 9b, and 15, respectively.The relative stereochemistry of marmelo oxides A and B was established by NOE measurements.
View MoreBuffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
Shanghai HengXun Pharmaceutical Tech. Co., Ltd.
Contact:86-86-52730756
Address:Room 603, No. 240, Tianmuzhong Road, Zhabei, Shanghai, China
Contact:+86-574-89075960
Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Contact:+86-021-58123769
Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Anhui Biochem United Pharmaceutical Co., Ltd.
Contact:0086 551 5167062 / 5228268
Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Doi:10.1021/acs.orglett.7b00983
(2017)Doi:10.1007/BF01526809
(1900)Doi:10.1021/jf904093y
(2010)Doi:10.1021/ic9021036
(2010)Doi:10.1021/ja00198a052
(1989)Doi:10.1016/S0040-4020(01)86177-9
(1988)
