Alkyl Group Transfer from Rhodium(I) to Electrophilic Reagents; Inducement by a Tertiary Phosphine

DOI: 10.1039/c39890001008

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1008 - 1009 (1989)

Update date:2022-08-02

Topics:

Authors:

Johnston, Gregory G.

Baird, Michael C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890001008

Although the compound RhMe(CO) (1) is normally inert to methyl iodide, chlorotrimethyltin and acetone, it reacts in the presence of trimethylphosphine with (a) methyl iodide to form the cationic complex >(+) (2), and methane, and ethylene but not ethane, (b) chlorotrimethyltin to form (2) and tetramethyltin, and (c) acetone to form (2) and t-butoxide; the role of the trimethylphosphine seems to involve substituting one arm of the triphosphine, thus rendering the Rh-Me moiety more reactive towards electrophilic reagents.

Full text of DOI:10.1039/c39890001008

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Rh(CO)(PMe₃)(MeC(CH₂PPh₂)3)}⁽¹⁺⁾

Cas No:121373-91-9

R&D Labs maybe for 121373-91-9

Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
ZUNYI CITY BEI YUAN CHEMICAL CO., LTD

website:http://www.china-beiyuan.com

Contact:+86-851-27751258

Address:Shawan Town, Huichuan District, Zunyi City, Guizhou Province, China
Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County

Relevant to this article

2-Amino-3-methyl-6-[meth-yl-(phen-yl)-amino]-5-nitro-pyrimidin-4(3H)-one: Polarized mol-ecules within hydrogen-bonded sheets

Doi:10.1107/S010827010902887X
()
On the scope of trimethylaluminium-promoted 1,2-additions of ArZnX reagents to aldehydes

Doi:10.1002/chem.200901803
(2010)
Organoaluminum-catalyzed rearrangement of epoxides a facile route to the synthesis of optically active β-siloxy aldehydes

Doi:10.1016/S0040-4020(01)96153-8
(1991)
Pharmacomodulation d'arylacetones thiopheniques anti-agregantes plaquettaires

Doi:10.1016/0223-5234(88)90092-X
(1988)
Chemistry of cyclic aminooxycarbenes

Doi:10.1139/v97-154
(1997)
Structure and stereodynamics of aryldiimino derivatives

Doi:10.1021/jo100106t
(2010)

Article Doi