SILICON-ASSISTED SYNTHESIS OF BRIDGED AZABICYCLIC SYSTEMS VIA N-ACILIMINIUM INTERMEDIATES

DOI: 10.1016/S0040-4020(01)90113-9

Source and publish data:

Tetrahedron p. 6729 - 6738 (1988)

Update date:2022-08-05

Topics:

Authors:

Klaver, Wim J.

Hiemstra, Henk

Speckamp, W. Nico

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Article abstract of DOI:10.1016/S0040-4020(01)90113-9

Intramolecular acid-mediated reactions of 2-propynyl- and allylsilanes with five- and six-membered cyclic N-acyliminium ion precursors lead to bridged azabicyclic compounds (Table I).Neat formic acid is the reaction medium of choice in most cases.The cycl

Full text of DOI:10.1016/S0040-4020(01)90113-9

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