Chemistry - A European Journal p. 18580 - 18583 (2015)
Update date:2022-09-26
Topics:
Lu, Qingquan
Peng, Pan
Luo, Yi
Zhao, Ying
Zhou, Minxian
Lei, Aiwen
A copper-catalyzed ketooxygenation of electron-deficient alkenes was developed. This approach combines O-H alkylation, aerobic decarboxylation, and oxygenation in one transformation. Mechanistic investigation of this reaction showed that the copper salt is responsible for both generating the amidoxyl radical and promoting aerobic decarboxylation.
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