Functionalization of 6,6-Dimethylfulvene: A Fulvene Analogue of the Aldol Condensation

DOI: 10.1016/S0040-4039(00)80663-2

Source and publish data:

Tetrahedron Letters p. 4997 - 5000 (1988)

Update date:2022-08-04

Topics:

Authors:

Nystroem, Jan-Erik

Bystroem, Styrbjoern E.

Ristola, Taina

Ekstroem, John

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80663-2

6,6-Dimethylfulvene 1 was regioselectively functionalized at the 7-position by reacting the fulvene anion 2 with aldehydes at low temperature.The adducts 3 were trapped at low temperature and isolated as fulvenols 4 or as the corresponding trimethylsilyl

Full text of DOI:10.1016/S0040-4039(00)80663-2

Products guided by the article

Product name:[1-(4-Chloro-phenyl)-3-cyclopenta-2,4-dienylidene-butoxy]-trimethyl-silane

Cas No:121896-58-0

R&D Labs maybe for 121896-58-0

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Nanjing Raise Pharmatech Co., Ltd

website:http://www.raisechem.com

Contact:+86-25-58649566

Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
WEIFANG DERUN CHEMICAL CO.,LTD

Contact:86-536-8956886

Address:weifang

Relevant to this article

New synthetic routes to biologically interesting geranylated flavanones and geranylated chalcones: First total synthesis of (±)-prostratol F, xanthoangelol, and (±)-lespeol

Doi:10.1002/hlca.200900251
(2010)
Exceptionally mild palladium(II)-catalyzed dehydrogenative C-H/C-H arylation of indolines at the C-7 position under air

Doi:10.1021/ol503035z
(2014)
Enantioselective synthesis of 2,3-dihydro-1H-benzo [b]azepines: Iridium-catalyzed tandem allylic vinylation/amination reaction

Doi:10.1002/anie.200906638
(2010)
Synthesis of Substituted Acridines through a Palladium-Catalyzed Condensation/Cyclization/Tautomerization Sequence

Doi:10.1002/ejoc.201601553
(2017)
Synthesis, crystal structures and photoluminescence of 7-(N,N′-diethylamino)-3-phenylcoumarin derivatives

Doi:10.1016/j.saa.2009.12.049
()
Syntheses of Destomic Acid and Anhydrogalantinic Acid from L-Serinal

Doi:10.1021/jo00026a031
(1991)

Article Doi