Functionalization of 6,6-Dimethylfulvene: A Fulvene Analogue of the Aldol Condensation

DOI: 10.1016/S0040-4039(00)80663-2

Source and publish data:

Tetrahedron Letters p. 4997 - 5000 (1988)

Update date:2022-08-04

Topics:

Authors:

Nystroem, Jan-Erik

Bystroem, Styrbjoern E.

Ristola, Taina

Ekstroem, John

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Article abstract of DOI:10.1016/S0040-4039(00)80663-2

6,6-Dimethylfulvene 1 was regioselectively functionalized at the 7-position by reacting the fulvene anion 2 with aldehydes at low temperature.The adducts 3 were trapped at low temperature and isolated as fulvenols 4 or as the corresponding trimethylsilyl

Full text of DOI:10.1016/S0040-4039(00)80663-2

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