Activation of allylic C-F bonds: Palladium-catalyzed allylic amimation of 3,3-difluoropropenes

DOI: 10.1002/anie.200904747

Source and publish data:

Angewandte Chemie - International Edition p. 1123 - 1127 (2010)

Update date:2022-08-04

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Authors:

Pigeon, Xavier

Bergeron, Maxime

Barabe, Francis

Dube, Pascal

Frost, Heather N.

Paquin, Jean-Francois

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Article abstract of DOI:10.1002/anie.200904747

(Chemical Equation Present) Lose one, keep one! A wide range of cyclic and acyclic ss-aminofluoroalkenes are prepared by the title reaction. The key fluorinated palladium π-allyl intermediate is generated using a catalytic allylic C-F bond activation.

Full text of DOI:10.1002/anie.200904747

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