Octahedral metal carbonyls LXV. Olefin isomerization in (2-allylphenyldiphenylphosphine)tetracarbonyltungsten(0)

DOI: 10.1016/0022-328X(88)80675-2

Source and publish data:

Journal of Organometallic Chemistry p. 77 - 84 (1988)

Update date:2022-09-26

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Authors:

Wang, I-Hsiung

Dobson, Gerard R.

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Article abstract of DOI:10.1016/0022-328X(88)80675-2

The stepwise displacement of pip (=piperidine) from cis-(pip)2W(CO)4 by 2-allylphenyldiphenylphosphine (adpp) affords cis(η³-adpp)W(CO)4 (1) when the cis-(pip)(η¹-adpp)W(CO)4 intermediate (2; adpp is P-bonded) is isolated and purifie

Full text of DOI:10.1016/0022-328X(88)80675-2

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