Tetrahedron p. 349 - 362 (1989)
Update date:2022-08-02
Topics:
Matsuzawa, Satoshi
Horiguchi, Yoshiaki
Nakamura, Eiichi
Kuwajima, Isao
Trialkylsilyl chlorides, particularly in combination with hexamethylphosphoramide or 4-dimethylaminopyridine, dramatically accelerates the conjugate addition of catalytic and stoichiometric organocopper reagents onto enones, enals, and enoates, in which very high degrees of stereo- and chemoselectivities were observed.
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