REVISIT TO MEINWALD REARRANGEMENT OF ELECTRON-DEFICIENT SYSTEMS

DOI: 10.1016/S0040-4039(00)82334-5

Source and publish data:

Tetrahedron Letters p. 6313 - 6316 (1988)

Update date:2022-08-05

Topics:

Authors:

Niwayama, Satomi

Kobayashi, Susumu

Ohno, Masaji

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Article abstract of DOI:10.1016/S0040-4039(00)82334-5

The monoester 6, generated in situ by the enzymatic hydrolysis of the symmetric diester 5a with pig liver esterase, undergoes extremely facile Meinwald-type rearrangement to afford the bicyclo<3.1.0>hex-2-ene derivative 8a in quantitative yield.

Full text of DOI:10.1016/S0040-4039(00)82334-5

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Product name:(1S,5R,6S)-6-((S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionyloxymethyl)-bicyclo[3.1.0]hex-2-ene-1,2-dicarboxylic acid 1-ethyl ester 2-methyl ester

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