
Tetrahedron Letters p. 257 - 260 (1989)
Update date:2022-08-03
Topics: Epoxidation Experimental terms Enol Ethers Oxidation state Oxidations
Troisi, Luigino
Cassidei, Luigi
Lopez, Luigi
Mello, Rossella
Curci, Ruggero
Isolated methyl trifluoromethyl dioxirane 4b has been employed to achieve the rapid, low temperature epoxidation of enol ethers, such as alkoxy(aryl)methylidene adamantanes 1a-e and methoxy(2-naphtyl)methylidene 2-bornane 1f, affording the corresponding spirooxiranes in excellent (92-97percent) yields.
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