Tetrahedron Letters p. 2797 - 2800 (1989)
Update date:2022-07-29
Topics:
Burger, Ulrich
Erne-Zellweger, Dominique
Sledeski, Adam W.
Schmidlin, Serge
Pyrolysis (fvp) of a strained γ-sultine (3) produced 1H-indene-1-carboxaldehyde (8) and naphthalene.The key step in the production of aldehyde (8) involves a 1,3-dipolar cycloreversion, as evidenced by the trapping of an intermediate sulfene (6) with methyl acrylate.A diradical pathway is proposed for the formation of naphthalene.
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