On the Origin of Diastereoselection in the Cyclization of Enynes on Low-Valent Zirconium Centers. Substituent and Torsional Effects on Annulation Stereochemistry

DOI: 10.1021/jo00280a005

Source and publish data:

Journal of Organic Chemistry p. 4487 - 4488 (1989)

Update date:2022-07-30

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Authors:

Lund, Eric C.

Livinghouse, Tom

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Article abstract of DOI:10.1021/jo00280a005

A variety of substituted enynes have been found to undergo reductive cyclization mediated by zirconocene complexes with excellent degrees of stereoselection.

Full text of DOI:10.1021/jo00280a005

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