Journal of the American Chemical Society p. 7399 - 7402 (1989)
Update date:2022-07-30
Topics:
Bogey, Marcel
Demuynck, Claire
Destombes, Jean-Luc
Gaumont, Annie
Denis, Jean-Marc
et al.
The elusive monomeric thioformyl cyanide HCSCN, a possibly cosmic species, has been generated in the gas phase, either by flash-thermolytic retroene reaction of allylcyanomethyl sulfide or by vacuum gas-solid dehydrochlorination of cyanomethylsulfenyl chloride over potassium carbonate.An investigation by millimeter wave spectroscopy led to unambiguous identification, molecular constants, and lifetime of HCSCN.
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