Organometallics p. 2069 - 2074 (1987)
Update date:2022-08-04
Topics:
Hansen, Marvin M.
Bartlett, Paul A.
Heathcock, Clayton H.
The preparation, characterization, and reactivity of ethylzinc enolate 3 are reported. Enolate 3 is less reactive than the corresponding lithium enolate but undergoes many of the same reactions. The unprecedented protonation of 3 by secondary amines is reported. The metal exchange reaction used to prepare 3 is not a general method for the preparation of other alkylzinc enolates.
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