Reversal of Stereochemistry in the Aldol Reactions of a Chiral Boron Enolate

DOI: 10.1021/jo00288a029

Source and publish data:

Journal of Organic Chemistry p. 173 - 181 (1990)

Update date:2022-08-04

Topics:

Authors:

Danda, Hidenori

Hansen, Marvin M.

Heathcock, Clayton H.

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Article abstract of DOI:10.1021/jo00288a029

A novel route to optically active anti aldols of certain aldehydes is presented.The boron enolate derived from oxazolidinone 3 reacts with various aldehydes to give either syn or anti aldols, depending on the amount of dibutylboron triflate used in the en

Full text of DOI:10.1021/jo00288a029

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