FACILE SYNTHESIS OF A SUBSTITUTED BICYCLONONANE VIA AN ANIONIC -SIGMATROPIC SHIFT: USE OF RANGE 2D HETCOR AND DIFFERENCE NOE IN STRUCTURE DETERMINATION

DOI: 10.1016/S0040-4039(01)80270-7

Source and publish data:

Tetrahedron Letters p. 641 - 644 (1989)

Update date:2022-09-26

Topics:

Authors:

Jung, Michael E.

Kaas, Susan M.

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Article abstract of DOI:10.1016/S0040-4039(01)80270-7

The structure of the exo-alkenyl norbornenol 16x (prepared in good yield from the ketone 11) was proven by HETCOR and difference NOE of 15x; it rearranges readily to the substituted bicyclo<4.2.1>non-7-en-3-one 17.

Full text of DOI:10.1016/S0040-4039(01)80270-7

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