Final solution on the long-standing structural arguments on the c-3 stereochemistries of three glucoindole alkaloids: Palicoside, dolichantoside, and isodolichantoside - Through chemical conversions and spectroscopic studies

DOI: 10.1016/S0040-4039(98)01686-4

Source and publish data:

Tetrahedron Letters p. 7737 - 7740 (1998)

Update date:2022-08-05

Topics:

Authors:

Ohmori, Osamu

Kumazawa, Kyoko

Hoshino, Hiroyuki

Suzuki, Takako

Morishima, Yuka

Kohno, Hiroko

Kitajima, Mariko

Sakai, Shin-Ichiro

Takayama, Hiromitsu

Aimi, Norio

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Article abstract of DOI:10.1016/S0040-4039(98)01686-4

Three natural strictosidine/vincoside-class glucoindole alkaloids have been chemically correlated with strictosidinic acid possessing a rigorously established stereostructure. The C-3 stereochemistry of palicoside, dolichantoside, and isodolichantoside has been firmly proved to be (S), (S), and (R), respectively.

Full text of DOI:10.1016/S0040-4039(98)01686-4

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