SYNTHETIC STUDIES ON THE ESPERAMICIN/CALICHEAMICIN ANTITUMOR ANTIBIOTICS. SELENIUM DIOXIDE OXIDATION OF A BRIDGEHEAD TRIALKYLSILYL ENOL ETHER

DOI: 10.1016/S0040-4039(01)80468-8

Source and publish data:

Tetrahedron Letters p. 3637 - 3640 (1989)

Update date:2022-08-05

Topics:

Authors:

Magnus, Philip

Bennett, Frank

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Article abstract of DOI:10.1016/S0040-4039(01)80468-8

Oxidation of the bridgehead t-butyldimethylsilyl enol ether 4 with selenium dioxide at 25 deg C produces the stable hemihydrate 6, which on further oxidation gave the allylic alcohol 8.

Full text of DOI:10.1016/S0040-4039(01)80468-8

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