Journal of the American Chemical Society p. 6413 - 6422 (2021)
Update date:2022-08-03
Topics: Chiral TMS Asymmetric Racemic Borylation C2-symmetrical
Imamoto, Tsuneo
Ito, Hajime
Iwamoto, Hiroaki
Ozawa, Yu
Takenouchi, Yuta
A new C2-symmetrical P-chirogenic bisphosphine ligand with silyl substituents on the ligand backbone, (R,R)-5,8-TMS-QuinoxP*, has been developed. This ligand showed higher reactivity and enantioselectivity for the direct enantioconvergent borylation of cy
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