Diazo Compounds. 72. Diazoalkylphosphanes - Synthesis by Electrophilic Diazoalkane Substitution and Oxidative Addition Reactions at Phosphorus

DOI: 10.1002/prac.19933350704

Source and publish data:

Journal fur Praktische Chemie - Chemiker-Zeitung p. 589 - 598 (1993)

Update date:2022-09-26

Topics:

Authors:

Nees, Hans-Joachim

Keller, Harald

Facklam, Thomas

Herrmann, Albert

Welsch, Jochen

et al. et al.

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Article abstract of DOI:10.1002/prac.19933350704

Electrophilic diazoalkane substitution of the diazomethyl compounds 1a,b with the chloro phosphanes 2a-o in the presence of lithium diethylamide yields the diazoalkyl phosphanes 3a-z.Oxidative addition of oxygen, sulfur and selenium at phosphorus leads in

Full text of DOI:10.1002/prac.19933350704

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