Bi-, Tetra-, and Poly-nuclear Complexes of Gold(I) and Silver(I) with Bis(diphenylphosphino)-methanide or -amide acting as Six-electron Donors

DOI: 10.1039/DT9890001883

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1883 - 1886 (1989)

Update date:2022-08-03

Topics:

Authors:

Uson, Rafael

Laguna, Antonio

Laguna, Mariano

Gimeno, Concepcion

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Article abstract of DOI:10.1039/DT9890001883

The reaction of or ClO4 with bis(diphenylphosphino)amine, bis(diphenylphosphino)methane, or bis(diphenylthiophosphoryl)amine leads to neutral complexes , 2N> (3), (4), or 2N> (5).Complexes (1), (2), and (4) react further with gold or silver complexes giving tetranuclear ring-system derivatives in which the amido or methanido ligand is acting as a six-electron donor ligand.

Full text of DOI:10.1039/DT9890001883

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