Synthesis of enantioenriched indolopiperazinones via iridium(i) n-heterocyclic carbene complex catalyzed asymmetric intramolecular allylic amination reaction

Article abstract of DOI:10.3987/COM-16-S(S)19

Systematic study on employing the D-camphor derived carbenes as the chiral ligands in iridium-catalyzed intramolecular allylic amination reaction was carried out. Under mild reaction conditions, enantioenriched indolopiperazinones were obtained in good yi

Full text of DOI:10.3987/COM-16-S(S)19

Supporting Information for
SYNTHESIS OF ENANTIOENRICHED INDOLOPIPERAZINONES
VIA IRIDIUM(I) N-HETEROCYCLIC CARBENE COMPLEX
CATALYZED ASYMMETRIC INTRAMOLECULAR ALLYLIC
AMINATION REACTION
Ke-Yin Ye, Ke-Jia Wu, Guo-Tai Li, Li-Xin Dai and Shu-Li You*
State Key Laboratory of Organometallic Chemistry
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
345 Lingling Lu, Shanghai 200032, China
E-mail: slyou@sioc.ac.cn
Table of Contents
Copies of NMR spectra and HPLC chromatographs
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X-ray data of complex C1-C3
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2a
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2i
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