Organic Letters p. 5498 - 5501 (2010)
Update date:2022-07-29
Topics:
Lumbroso, Alexandre
Vautravers, Nicolas R.
Breit, Bernhard
The selective intermolecular anti-Markovnikov addition of carboxylic acids to terminal alkynes yielding valuable Z-enol esters has been achieved for the first time under rhodium-catalyzed conditions. The catalyst system is applicable to a broad substrate
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